Chosen physical properties of low acetylated starch esterificated with oleic acid

Tomasz Boruczkowski

wbinoz@upwr.edu.pl
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)

Hanna Boruczkowska


Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)

Maciej Bienkiewicz


Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)

Wioletta Dróżdż


Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)

Ewa Tomaszewska-Ciosk


Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)

Piotr Regiec


Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)

Abstract

In this study, we conducted an enzymatic esterification of low acetylated starch by fatty acid using enzymes in an organic solvent. We analyzed both the starting materials and reaction products formed in the esterification. The reaction of esterification using lipase from Candida antarctica and two separate enzyme fractions (A and B) formed three acetylated starch esters of oleic acid. The degree of substitution determined by 1HNMR spectrum analysis ranged from 0.07 to 0.12, and was dependent on the applied fraction of the enzyme. Thermal analysis using differential scanning calorimeter showed that the products’ heats of phase transition were higher than the acetylated starch heat of phase transition. A degree of substitution of acetylated starch had a significant impact on the physical properties of investigated compounds.

Supporting Agencies

Work carried out under the grant of the Ministry of Science and Higher Education, contract No. 2338/B/P01/2009/36 for the implementation of the research project No. NN312233836

Keywords:

esterification, lipase, oleic acid, starch

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Published
2012-12-31

Cited by

Boruczkowski, T. (2012) “Chosen physical properties of low acetylated starch esterificated with oleic acid”, Bulletin of Plant Breeding and Acclimatization Institute, (266), pp. 191–203. doi: 10.37317/biul-2012-0019.

Authors

Tomasz Boruczkowski 
wbinoz@upwr.edu.pl
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland

Authors

Hanna Boruczkowska 

Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland

Authors

Maciej Bienkiewicz 

Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland

Authors

Wioletta Dróżdż 

Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland

Authors

Ewa Tomaszewska-Ciosk 

Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland

Authors

Piotr Regiec 

Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland

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Copyright (c) 2012 Tomasz Boruczkowski, Hanna Boruczkowska, Maciej Bienkiewicz, Wioletta Dróżdż, Ewa Tomaszewska-Ciosk, Piotr Regiec

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