Chosen physical properties of low acetylated starch esterificated with oleic acid
Tomasz Boruczkowski
wbinoz@upwr.edu.plKatedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)
Hanna Boruczkowska
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)
Maciej Bienkiewicz
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)
Wioletta Dróżdż
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)
Ewa Tomaszewska-Ciosk
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)
Piotr Regiec
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu (Poland)
Abstract
In this study, we conducted an enzymatic esterification of low acetylated starch by fatty acid using enzymes in an organic solvent. We analyzed both the starting materials and reaction products formed in the esterification. The reaction of esterification using lipase from Candida antarctica and two separate enzyme fractions (A and B) formed three acetylated starch esters of oleic acid. The degree of substitution determined by 1HNMR spectrum analysis ranged from 0.07 to 0.12, and was dependent on the applied fraction of the enzyme. Thermal analysis using differential scanning calorimeter showed that the products’ heats of phase transition were higher than the acetylated starch heat of phase transition. A degree of substitution of acetylated starch had a significant impact on the physical properties of investigated compounds.
Supporting Agencies
Keywords:
esterification, lipase, oleic acid, starchReferences
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Authors
Tomasz Boruczkowskiwbinoz@upwr.edu.pl
Katedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland
Authors
Hanna BoruczkowskaKatedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland
Authors
Maciej BienkiewiczKatedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland
Authors
Wioletta DróżdżKatedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland
Authors
Ewa Tomaszewska-CioskKatedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland
Authors
Piotr RegiecKatedra Technologii Rolnej i Przechowalnictwa, Uniwersytet Przyrodniczy we Wrocławiu Poland
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Copyright (c) 2012 Tomasz Boruczkowski, Hanna Boruczkowska, Maciej Bienkiewicz, Wioletta Dróżdż, Ewa Tomaszewska-Ciosk, Piotr Regiec
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